A student constructs a galvanic cell that has a chromium, Cr, electrode in a compartment containing a 1.0 M chromium(II) nitrate, \(\ce{Cr(NO3)2}\) , solution and a silver, Ag, electrode in a compartment containing 1.0 M silver nitrate, \(\ce{AgNO3}\) , solution. A salt bridge containing a 1.0 M potassium chloride, KCl, solution connects the two compartments. When the student measures the cell potential, the value is far from the ideal predicted value. What is the cause of this discrepancy?

A.
The initial concentrations should have been lower than 1.0 M.
B.
The initial concentrations should have been higher than 1.0 M.
C.
The potassium chloride in the salt bridge interfered with the reaction.
D.
The student did not allow the cell to come to equilibrium
Chemistry
AP
College Board
Exam No:AP Chemistry Problem Set 7 Year:2024 Question No:APChemistry2024AP0224

Answer:

C

Knowledge points:

9.10 Cell Potential Under Nonstandard Conditions

Solution:

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