Benzene reacts with bromine in the presence of an aluminium bromide catalyst, $$\(\mathrm{AlBr}_{3}\)$$, to form bromobenzene. This is a substitution reaction. No addition reaction takes place. Explain why no addition reaction takes place. $$\(\mathrm{AlBr}_{3}\)$$ reacts with bromine to generate an electrophile, $$\(\mathrm{Br}^{+}\)$$.

Chemistry
IGCSE&ALevel
CAIE
Exam No:9701_s20_qp_43 Year:2020 Question No:5(a)(i)

Answer:

The substitution product is stabilised by delocalisation of (6) \(\pi\)-electrons

OR

The addition product is not stabilised by delocalisation of \((6) \pi\)-electrons [1]

Knowledge points:

30.1.2.2 with regards to the effect of delocalisation (aromatic stabilisation) of electrons in arenes to explain the predomination of substitution over addition

Solution:

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