Explain why trichloroethanoic acid, $$\(\mathrm{CCl}_{3} \mathrm{COOH}\)$$, is more acidic than ethanoic acid, $$\(\mathrm{CH}_{3} \mathrm{COOH}\)$$. ............................................................................................................................................... . ............................................................................................................................................... . .........................................................................................................................................

Chemistry
IGCSE&ALevel
CAIE
Exam No:9701_s24_qp_42 Year:2024 Question No:9(a)

Answer:



Knowledge points:

33.1.1.1 reaction of an alkylbenzene with hot alkaline KMnO4 and then dilute acid, exemplified by methylbenzene
33.1.2 describe the reaction of carboxylic acids with PCl 3 and heat, PCl 5, or SOCl 2 to form acyl chlorides
33.1.3.1 the oxidation of methanoic acid, HCOOH, with Fehling’s reagent or Tollens’ reagent or acidified KMnO4 or acidified K2Cr2O7 to carbon dioxide and water
33.1.3.2 the oxidation of ethanedioic acid, HOOCCOOH, with warm acidified KMnO4 to carbon dioxide
33.1.4 describe and explain the relative acidities of carboxylic acids, phenols and alcohols
33.1.5 describe and explain the relative acidities of chlorine-substituted carboxylic acids

Solution:

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