Iron is a transition element in the fourth period. Iron forms compounds containing the ions $$\(\mathrm{Fe}^{2+}\)$$ and $$\(\mathrm{Fe}^{3+}\)$$. When an excess of $$\(\mathrm{CN}^{-}(\mathrm{aq})\)$$ ions is added to green $$\(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}(\mathrm{aq})\)$$ ions, yellow $$\(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{4-}\)$$ complex ions are formed. Heating $$\(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{4-}\)$$ with dilute nitric acid and then neutralising the product with $$\(\mathrm{Na}_{2} \mathrm{CO}_{3}(\mathrm{aq})\)$$ produces red crystals, containing the $$\(\left[\mathrm{Fe}(\mathrm{CN})_{5} \mathrm{NO}\right]^{2-}\)$$ complex ion. $$\(\mathrm{NO}\)$$ is a neutral, monodentate ligand. Deduce the oxidation states of iron in: $$\( \left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{4-} \ldots \ldots \ldots \ldots \ldots \ldots \ldots \ldots \ldots \ldots \ldots \ldots\left(\mathrm{Fe}(\mathrm{CN})_{5} \mathrm{NO}\right]^{2-}\ldots \ldots \ldots \ldots \ldots \ldots \ldots \ldots \ldots \ldots\ldots \)$$
Exam No:9701_m20_qp_42 Year:2020 Question No:1(b)(iii)
Answer:
\(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{4}\) is \((+) 2 \quad\left[\mathrm{Fe}(\mathrm{CN})_{5} \mathrm{NO}^{2-}\right.\) is \((+) 3\)
Knowledge points:
28.2.1 describe and explain the reactions of transition elements with ligands to form complexes, including the complexes of copper(II) and cobalt(II) ions with water and ammonia molecules and hydroxide and chloride ions
Solution:
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