Potassium iodide, KI, is used as a reagent in both inorganic and organic chemistry. A student electrolyses a solution of $$\(\mathrm{KI}(\mathrm{aq})\)$$ for 8 minutes using a direct current. The half-equation for the reaction that occurs at the anode is given. $$\[ 2 \mathrm{I}^{-}(\mathrm{aq}) \rightarrow \mathrm{I}_{2}(\mathrm{aq})+2 \mathrm{e}^{-} \]$$ (i) Write a half-equation for the reaction that occurs at the cathode. Include state symbols. ................................................................................................................................. (ii) After the electrolysis, the $$\(\mathrm{I}_{2}(\mathrm{aq})\)$$ produced requires $$\(21.35 \mathrm{~cm}^{3}\)$$ of $$\(0.100 \mathrm{moldm}^{-3}\)$$ $$\(\mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}(\mathrm{aq})\)$$ to react completely. $$\[ \mathrm{I}_{2}(\mathrm{aq})+2 \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}(\mathrm{aq}) \rightarrow 2 \mathrm{NaI}(\mathrm{aq})+\mathrm{Na}_{2} \mathrm{~S}_{4} \mathrm{O}_{6}(\mathrm{aq}) \]$$ Calculate the average current used in 8 minutes during the electrolysis. current $$\(=\)$$ .................................................... A
Exam No:9701_m24_qp_42 Year:2024 Question No:1(d)
Answer:

Knowledge points:
13.2.1.1 homologous series
13.2.1.2 saturated and unsaturated
13.2.1.3 homolytic and heterolytic fission
13.2.1.4 free radical, initiation, propagation, termination (the use of arrows to show movement of single electrons is not required)
13.2.1.5 nucleophile, electrophile, nucleophilic, electrophilic
13.2.1.6 addition, substitution, elimination, hydrolysis, condensation
13.2.1.7 oxidation and reduction (in equations for organic redox reactions, the symbol [O] can be used to represent one atom of oxygen from an oxidising agent and the symbol [H] one atom of hydrogen from a reducing agent)
13.2.2.1 free-radical substitution
13.2.2.2 electrophilic addition
13.2.2.3 nucleophilic substitution
13.2.2.4 nucleophilic addition (in organic reaction mechanisms, the use of curly arrows to represent movement of electron pairs is expected; the arrow should begin at a bond or a lone pair of electrons)
6.1.1 calculate oxidation numbers of elements in compounds and ions
6.1.2 use changes in oxidation numbers to help balance chemical equations
6.1.3 explain and use the terms redox, oxidation, reduction and disproportionation in terms of electron transfer and changes in oxidation number
6.1.4 explain and use the terms oxidising agent and reducing agent
6.1.5 use a Roman numeral to indicate the magnitude of the oxidation number of an element
Solution:
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