Table 1.1 shows some energy changes. (i) Born-Haber cycles can be used to determine the lattice energies of ionic compounds. Complete the Born-Haber cycle in Fig. 1.1 for potassium sulfide, $$\(\mathrm{K}_{2} \mathrm{~S}(\mathrm{~s})\)$$. Include state symbols for all of the species. ......................................... (ii) Calculate the lattice energy, $$\(\Delta H_{\text {latt }}^{\theta}\)$$, of $$\(\mathrm{K}_{2} \mathrm{~S}(\mathrm{~s})\)$$ using relevant data from Table 1.1. Show your working. $$\[ \Delta H_{\text {latt }}^{\ominus} \text { of } \mathrm{K}_{2} \mathrm{~S}(\mathrm{~s})= \]$$ .......................... $$\(\mathrm{kJ} \mathrm{mol}^{-1}\)$$

Chemistry
IGCSE&ALevel
CAIE
Exam No:9701_s24_qp_42 Year:2024 Question No:1(d)

Answer:





Knowledge points:

23.2.1 define and use the term enthalpy change with reference to hydration, and solution, Δ$\mathrm{H}_{sol}$
23.2.2 construct and use an energy cycle involving enthalpy change of solution, lattice energy and enthalpy change of hydration
23.2.3 carry out calculations involving the energy cycles in 23.2.2
23.2.4 explain, in qualitative terms, the effect of ionic charge and of ionic radius on the numerical magnitude of an enthalpy change of hydration

Solution:

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