The diagram shows the mass spectrum of a sample of chlorine. Peaks $$\(\mathrm{V}, \mathrm{W}, \mathrm{X}, \mathrm{Y}\)$$ and Z are labelled. Which statements about this spectrum are correct? 1 The relative atomic mass of chlorine can be calculated from the abundances and $$\(\mathrm{m} / \mathrm{e}\)$$ values of 2 of the 5 peaks. $$\(2 \quad 37.0 \mathrm{~g}\)$$ of the species responsible for peak Z contains $$\(3.011 \times 10^{23}\)$$ molecules. 3 The relative molecular mass of chlorine can be calculated from the abundances and $$\(m / e\)$$ values of peaks $$\(X, Y\)$$ and $$\(Z\)$$.

A.
1, 2 and 3
B.
1 and 2 only
C.
1 and 3 only
D.
2 and 3 only
Chemistry
IGCSE&ALevel
CAIE
Exam No:9701_w24_qp_11 Year:2024 Question No:40

Answer:

A

Knowledge points:

11.2.1 describe the relative reactivity of the elements as oxidising agents
11.2.2 describe the reactions of the elements with hydrogen and explain their relative reactivity in these reactions
11.2.3 describe the relative thermal stabilities of the hydrogen halides and explain these in terms of bond strengths
22.2.1 analyse mass spectra in terms of m/e values and isotopic abundances (knowledge of the working of the mass spectrometer is not required)
22.2.2 calculate the relative atomic mass of an element given the relative abundances of its isotopes, or its mass spectrum
22.2.3 deduce the molecular mass of an organic molecule from the molecular ion peak in a mass spectrum
22.2.4 suggest the identity of molecules formed by simple fragmentation in a given mass spectrum
22.2.5 deduce the number of carbon atoms, n, in a compound using the M +1 peak and the formula
22.2.6 deduce the presence of bromine and chlorine atoms in a compound using the M +2 peak

Solution:

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