This question is about an experiment to investigate the effect of temperature on the equilibrium constant, $$\(K_{1}\)$$, of the reaction shown. $$\[ \mathrm{Fe}^{3+}(\mathrm{aq})+\mathrm{SCN}^{-}(\mathrm{aq}) \rightleftharpoons \mathrm{FeSCN}^{2+}(\mathrm{aq}) \]$$ The data collected is used to determine the value of the enthalpy change of the reaction. To set up the equilibrium, aqueous iron(III) nitrate, $$\(\mathrm{Fe}\left(\mathrm{NO}_{3}\right)_{3}(\mathrm{aq})\)$$, is mixed with aqueous potassium thiocyanate, $$\(\mathrm{KSCN}(\mathrm{aq})\)$$. Aqueous iron thiocyanate ions, $$\(\operatorname{FeSCN}^{2+}(\mathrm{aq})\)$$, have a red colour. A colorimeter is used to measure the absorbance of the reaction mixture. A calibration graph can then be used to determine the concentration of $$\(\mathrm{FeSCN}^{2+}(\mathrm{aq})\)$$ in the reaction mixture. Table 2.1 shows the solutions for the experiments. Describe how you would prepare $$\(100.0 \mathrm{~cm}^{3}\)$$ of solution B from solution $$\(\mathbf{A}\)$$. Include a calculation of the volume of solution A required for the preparation of solution B. Give the name and capacity of any key apparatus that should be used. Write your answer as a series of numbered steps. ............................................................................................................................................... . ............................................................................................................................................... . ............................................................................................................................................... . ............................................................................................................................................... . ............................................................................................................................................... . ............................................................................................................................................... . .........................................................................................................................................
Exam No:9701_s24_qp_52 Year:2024 Question No:2(a)
Answer:
Knowledge points:
2.4.1.1 reacting masses (from formulae and equations) including percentage yield calculations
2.4.1.2 volumes of gases (e.g. in the burning of hydrocarbons)
2.4.1.3 volumes and concentrations of solutions
2.4.1.4 limiting reagent and excess reagent (When performing calculations, candidates’ answers should reflect the number of significant figures given or asked for in the question. When rounding up or down, candidates should ensure that significant figures are neither lost unnecessarily nor used beyond what is justified (see also Mathematical requirements section).) deduce stoichiometric relationships from calculations such as those in 2.4.1 (1)–(4)
Solution:
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