When ammonium compounds are heated with sodium hydroxide or calcium hydroxide, ammonia is liberated. The ionic equation for the reaction is shown. $$\[ \mathrm{NH}_{4}^{+}+\mathrm{OH}^{-} \rightarrow \mathrm{NH}_{3}+\mathrm{H}_{2} \mathrm{O} \]$$ FA 1 is prepared by heating $$\(10.0 \mathrm{~cm}^{3}\)$$ of aqueous ammonium chloride, $$\(\mathrm{NH}_{4} \mathrm{Cl}(\mathrm{aq})\)$$, with $$\(25.0 \mathrm{~cm}^{3}\)$$ of $$\(2.00 \mathrm{moldm}^{-3}\)$$ sodium hydroxide, NaOH . The sodium hydroxide is in excess. The reaction mixture is cooled and diluted to $$\(250 \mathrm{~cm}^{3}\)$$ with distilled water. You will determine the concentration of the aqueous solution of ammonium chloride by titrating the remaining sodium hydroxide from the preparation of FA 1 with a known concentration of sulfuric acid. $$\[ 2 \mathrm{NaOH}(\mathrm{aq})+\mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{aq}) \rightarrow \mathrm{Na}_{2} \mathrm{SO}_{4}(\mathrm{aq})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \]$$ FA 2 is 0.0520 mol dm $$\(^{-3}\)$$ sulfuric acid, $$\(\mathrm{H}_{2} \mathrm{SO}_{4}\)$$. FA 3 is bromophenol blue indicator. From your accurate titration results, calculate a suitable mean value to use in your calculations. Show clearly how you obtain the mean value. $$\[ 25.0 \mathrm{~cm}^{3} \text { of FA } 1 \text { required } \]$$ .......................... $$\(\mathrm{cm}^{3}\)$$ of FA 2.
Exam No:9701_s24_qp_33 Year:2024 Question No:(b)
Answer:

Knowledge points:
2.4.1.1 reacting masses (from formulae and equations) including percentage yield calculations
2.4.1.2 volumes of gases (e.g. in the burning of hydrocarbons)
2.4.1.3 volumes and concentrations of solutions
2.4.1.4 limiting reagent and excess reagent (When performing calculations, candidates’ answers should reflect the number of significant figures given or asked for in the question. When rounding up or down, candidates should ensure that significant figures are neither lost unnecessarily nor used beyond what is justified (see also Mathematical requirements section).) deduce stoichiometric relationships from calculations such as those in 2.4.1 (1)–(4)
Solution:
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