Transition metal compounds can show a number of different types of isomerism. Hydration isomerism is where different numbers of water molecules act as ligands. The name chromium (III) chloride is given to several chemical compounds with the formula $$\(\mathrm{CrCl}_{3} \cdot \mathrm{XH}_{2} \mathrm{O}\)$$, including a number of hydration isomers. Explain why the tetrahedral complex $$\(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right) \mathrm{ClBrI}\right]\)$$ exists as two optical isomers. (2) ................................................................................................................................................................................................................................................................................ ................................................................................................................................................................................................................................................................................ ................................................................................................................................................................................................................................................................................ ................................................................................................................................................................................................................................................................................ ................................................................................................................................................................................................................................................................................ (ii) Complete the diagram showing the two optical isomers of the tetrahedral complex. (1)
Exam No:wch15-01-que-20240113 Year:2024 Question No:17(d)
Answer:
An answer that makes reference to the following points:
- cobalt / central metal ion has four different groups / ligands attached to it
- giving (two) non-superimposable mirror images
An answer that makes reference to the following points:
- two structures drawn as mirror images
or
two structures drawn with two ligands swapped
- cobalt / central metal ion has four different groups / ligands attached to it
- giving (two) non-superimposable mirror images
An answer that makes reference to the following points:
- two structures drawn as mirror images
or
two structures drawn with two ligands swapped
Knowledge points:
17.Transition Metals and their Chemistry
Solution:
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